| No. | Portrait | Minister (Constituency)
 | Term of office | Political party | Ministry | Chief Minister | 
| From | To | Period | 
| Minister of State Excise | 
| 01 |  |  | T. R. Narawane (MLA for Kurla Constituency No. 174-
 Mumbai Suburban District)
 (Legislative Assembly)
 | 01 May 1960
 | 07 March 1962
 | 1 year, 310 days | Indian National Congress | Yashwantrao I |   Yashwantrao Chavan
 | 
| 02 |  |  | Balasaheb Desai (MLA for Patan Constituency No. 261-
 Satara District)
 (Legislative Assembly)
 | 08 March 1962
 | 19 November 1962
 | 256 days | Indian National Congress | Yashwantrao II | 
| 03 |  |  | Abdul Kader Salebhoy (MLA for Mumbai South Central Constituency No. 180-
 Mumbai City District)
 (Legislative Assembly)
 | 20 November 1962
 | 24 November 1963
 | 1 year, 4 days | Indian National Congress | Kannamwar l | Marotrao Kannamwar | 
| 04 |  |  | P. K. Sawant (MLA for Chiplun Constituency No. 265-
 Ratnagiri District)
 (Legislative Assembly)
 (Interim Chief Minister)
 | 25 November 1962
 | 04 December 1963
 | 9 days | Indian National Congress | Sawant I | P. K. Sawant | 
| 05 |  |  | D. S. Palaspagar (MLC for Elected by MLAs Constituency No. 19 -
 Bhandara District)
 (Legislative Council)
 | 05 December 1963
 | 01 March 1967
 | 3 years, 86 days | Indian National Congress | Vasantrao I |  Vasantrao Naik
 | 
| 06 |  |  | Shantilal Shah (MLA for Vile Parle Constituency No. 177-
 Mumbai Suburban District
 (Legislative Assembly)
 | 01 March 1967
 | 13 March 1972
 | 5 years, 12 days | Indian National Congress | Vasantrao II | 
| 07 |  |   | Pratibha Patil (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District)
 (Legislative Assembly)
 | 13 March 1972
 | 21 February 1975
 | 2 years, 345 days | Indian National Congress | Vasantrao III | 
| 08 |  | .jpg)  | Vasantdada Patil (MLC for Elected by MLAs Constituency No. 20 -
 Sangli District)
 (Legislative Council)
 | 21 February 1975
 | 17 May 1977
 | 2 years, 85 days | Indian National Congress | Shankarrao I |  Shankarrao Chavan
 | 
| 09 |  |  | Shankarrao Rakh (MLA for Badnapur Jalna Constituency No. 101-
 Jalna District)
 (Legislative Assembly)
 | 17 May 1977
 | 07 March 1978
 | 1 year, 294 days | Indian National Congress | Vasantdada I | .jpg) Vasantdada Patil
 | 
| 10 |  | .jpg)  | Vasantdada Patil (MLA for Sangli Constituency No. 282 -
 Sangli District)
 (Legislative Assembly)
 (Chief Minister)
 | 07 March 1978
 | 18 July 1978
 | 133 days | Indian National Congress (U) | Vasantdada II | 
| 11 |  |  | Sadanand Shankar Varde (MLA for Vandre Constituency No. 176-
 Mumbai Suburban District)
 (Legislative Assembly)
 | 18 July 1978
 | 17 February 1980
 | 1 year, 214 days | Janata Party | Pawar I | .jpg) Sharad Pawar
 | 
| 12 |  | .jpg)  | Abdul Rahman Antulay (MLA for Shrivardhan Constituency No. 193-
 Raigad District)
 (Legislative Assembly)
 (Chief Minister)
 | 09 June 1980
 | 21 January 1982
 | 1 year, 226 days | Indian National Congress | Antulay | .jpg)  Abdul Rahman Antulay
 | 
| 13 |  |   | Babasaheb Bhosale (MLA for Nehrunagar Constituency No. 172-
 Mumbai Suburban District)
 (Legislative Assembly)
 (Chief Minister)
 | 21 January 1982
 | 11 October 1982
 | 263 days | Indian National Congress | Bhosale |   Babasaheb Bhosale
 | 
| 14 |  |   | Pratibha Patil (MLA for Jalgaon City Constituency No. 13-
 Jalgaon District)
 (Legislative Assembly)
 | 11 October 1982
 | 02 February 1983
 | 114 days | Indian National Congress | 
| 15 |  |  | Baliram Waman Hiray (MLA for Dabhadi Constituency No. 74-
 Nashik District)
 (Legislative Assembly)
 | 07 February 1983
 | 05 March 1985
 | 2 years, 26 days | Indian National Congress | Vasantdada III | .jpg) Vasantdada Patil
 | 
| 16 |  |  | V. Subramanian (MLA for South Mumbai Constituency No. 121-
 Mumbai City District)
 (Legislative Assembly)
 | 12 March 1985 1960
 | 03 June 1985 1962
 | 83 days | Indian National Congress | Vasantdada IV | 
| 17 |  |  
 | Jawaharlal Darda (MLC for Elected by MLAs Constituency No. 19 -
 Yavatmal District)
 (Legislative Council)
 | 03 June 1985
 | 12 March 1986
 | 282 days | Indian National Congress | Nilangekar | Shivajirao Patil Nilangekar | 
| 18 |  | .jpg)  | Shankarrao Chavan (MLC for Elected by MLAs Constituency No. 08 -
 Nanded District)
 (Legislative Council)
 (Chief Minister)
 | 12 March 1986
 | 26 June 1988
 | 2 years, 106 days | Indian National Congress | Shankarrao II | .jpg)  Shankarrao Chavan
 | 
| 19 |  |  | Chhedilal Gupta (MLA for Gondiya Constituency No. 134-
 Gondiya District)
 (Legislative Assembly)
 | 26 June 1988
 | 03 March 1990
 | 1 year, 250 days | Indian National Congress | Pawar II |   Sharad Pawar
 | 
| 20 |  |  | Shankarrao Genuji Kolhe (MLA for Kopargaon Constituency No. 219-
 Ahmednagar District)
 (Legislative Assembly)
 | 04 March 1990
 | 25 June 1991
 | 1 year, 113 days | Indian National Congress | Pawar III | 
| 21 |  |  
 | Vijaysinh Mohite-Patil (MLA for Malshiras Constituency No. 254-
 Solapur District)
 (Legislative Assembly)
 | 25 June 1991
 | 30 December 1991
 | 188 days | Indian National Congress | Sudhakarrao | Sudhakarrao Naik | 
| 22 |  |  | Shankarrao Genuji Kolhe (MLA for Kopargaon Constituency No. 219-
 Ahmednagar District)
 (Legislative Assembly)
 | 30 December 1991
 | 22 February 1993
 | 1 year, 54 days | Indian National Congress | 
| 23 |  |   | Sharad Pawar (MLA for Baramati Constituency No. 201-
 Pune District)
 (Legislative Assembly)
 (Chief Minister)
 | 06 March 1993
 | 14 March 1995
 | 2 years, 8 days | Indian National Congress | Pawar IV |   Sharad Pawar
 | 
| 24 |  |  | Jagannath Patil (MLA for Kalyan Constituency No. 145-
 Thane District)
 (Legislative Assembly)
 | 14 March 1995
 | 31 January 1999
 | 3 years, 323 days | Bharatiya Janata Party | Joshi |   Manohar Joshi
 | 
| 25 |  | .jpg)  | Narayan Rane (MLA for Malvan Constituency No. 269-
 Sindhudurg District)
 (Legislative Assembly)
 (Chief Minister)
 | 01 February 1999
 | 11 May 1999
 | 99 days | Shiv Sena | Rane | .jpg)  Narayan Rane
 | 
| 26 |  |  | Anna Dange (MLC for Elected by MLAs Constituency No. 05 -
 Sangli District)
 (Legislative Council)
 | 11 May 1999
 | 17 October 1999
 | 159 days | Bharatiya Janata Party | 
| 27 |  |  | Vasant Chavan (MLC for Governor Nominated Constituency No. 11 -
 Pune District)
 (Legislative Council)
 | 19 October 1999
 | 16 January 2003
 | 3 years, 88 days | Nationalist Congress Party | Deshmukh I |   Vilasrao Deshmukh
 | 
| 28 |  | .jpg)  | Sushilkumar Shinde (MLA for Solapur South Constituency No. 251-
 Solapur District)
 (Legislative Assembly)
 (Chief Minister)
 | 18 January 2003
 | 01 November 2004
 | 1 year, 295 days | Indian National Congress | Sushilkumar | .jpg)  Sushilkumar Shinde
 | 
| 29 |  |  | Ganesh Naik (MLA for Belapur Constituency No. 151-
 Thane District)
 (Legislative Assembly)
 | 09 November 2004
 | 01 December 2007
 | 4 years, 22 days | Nationalist Congress Party | Deshmukh II |   Vilasrao Deshmukh
 | 
| 30 |  |  | Ganesh Naik (MLA for Belapur Constituency No. 151-
 Thane District)
 (Legislative Assembly)
 | 08 December 2008
 | 06 November 2009
 | 333 days | Nationalist Congress Party | Ashok I |  Ashok Chavan
 | 
| 31 |  |  | Ganesh Naik (MLA for Belapur Constituency No. 151-
 Thane District)
 (Legislative Assembly)
 | 07 November 2009
 | 10 November 201p
 | 1 year, 3 days | Nationalist Congress Party | Ashok II | 
| 32 |  |   | Prithviraj Chavan (MLC for Elected by MLAs Constituency No. 19 -
 Satara District)
 (Legislative Council)
 (Chief Minister)
 | 11 November 2010
 | 20 January 2012
 | 1 year, 70 days | Indian National Congress | Prithviraj |  Prithviraj Chavan
 | 
| 33 |  |  | Ganesh Naik (MLA for Belapur Constituency No. 151-
 Thane District)
 (Legislative Assembly)
 | 20 January 2012
 | 02 August 2014
 | 2 years, 194 days | Nationalist Congress Party | 
| 34 |  |   | Prithviraj Chavan (MLC for Elected by MLAs Constituency No. 19 -
 Satara District)
 (Legislative Council)
 (Chief Minister)
 | 02 August 2014
 | 26 September 2014
 | 55 days | Indian National Congress | 
| 35 |  |  | Eknath Khadse (MLA for Muktainagar Constituency No. 20-
 Jalgaon District)
 (Legislative Assembly)
 | 31 October 2014
 | 04 June 2016
 | 1 year, 217 days | Bharatiya Janata Party | Fadnavis I | .jpg)  Devendra Fadnavis
 | 
| 36 |  |   | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52-
 Nagpur District)
 (Legislative Assembly)
 (Chief Minister)
 (In Charge)
 | 04 June 2016
 | 08 July 2016
 | 30 days | Bharatiya Janata Party | 
| 37 |  |  | Chandrashekhar Bawankule (MLA for Kamthi Constituency No. 58-
 Nagpur District)
 (Legislative Assembly)
 | 08 July 2016
 | 12 November 2019
 | 3 years, 127 days | Bharatiya Janata Party | 
| 38 |  |   | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52-
 Nagpur District)
 (Legislative Assembly)
 (Chief Minister)
 (In Charge)
 | 23 November 2019
 | 28 November 2019
 | 5 days | Bharatiya Janata Party | Fadnavis II | 
| 39 |  |   | Chhagan Bhujbal (MLA for Yevla Constituency No. 119-
 Nashik District)
 (Legislative Assembly)
 | 28 November 2019
 | 30 December 2019
 | 32 days | Nationalist Congress Party | Thackeray | _(cropped).jpg)  Uddhav Thackeray
 | 
| 40 |  |   | Dilip Walse-Patil (MLA for Ambegaon Constituency No. 196-
 Pune District)
 (Legislative Assembly)
 | 30 December 2019
 | 05 April 2021
 | 1 year, 96 days | Nationalist Congress Party | 
| 41 |  |   | Ajit Pawar (MLA for Baramati Constituency No. 201-
 Pune District)
 (Legislative Assembly)
 (Deputy Chief Minister)
 | 05 April 2021
 | 29 June 2022
 | 1 year, 85 days | Nationalist Congress Party | 
| 42 |  |   | Eknath Shinde (MLA for Kopri-Pachpakhadi Constituency No. 147-
 Thane District)
 (Legislative Assembly)
 (Chief Minister)
 (In Charge)
 | 30 June 2022
 | 14 August 2022
 | 45 days | Shiv Sena (Shinde Group) | Eknath |   Eknath Shinde
 | 
| 43 |  |  | Shambhuraj Desai (MLA for Patan Constituency No. 261-
 Satara District)
 (Legislative Assembly)
 | 14 August 2022
 | 26 November 2024
 | 2 years, 104 days | Shiv Sena (Shinde Group) | 
| 44 |  |   | Devendra Fadnavis (MLA for Nagpur South West Constituency No. 52-
 Nagpur District)
 (Legislative Assembly)
 (Chief_Minister)
 In Charge
 | 05 December 2024
 | 21 December 2024
 | 16 days | Bharatiya Janata Party | Fadnavis III | .jpg)  Devendra Fadnavis
 | 
| 45 |  |   | Ajit Pawar (MLA for Baramati Constituency No. 201-
 Pune District
 (Legislative Assembly)
 (Deputy Chief Minister)
 | 21 December 2024
 | Incumbent | 243 days | Nationalist Congress Party (Ajit Pawar Group) |